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as ¹⁶O¹²C³²S and ¹⁶O¹²C³⁴S. This allows a set of simultaneous equations to be set up and solved for the bond lengths). A bond length obtained in this way is slightly different from the equilibrium bond length. This is because there is zero-point energy in the vibrational ground state, to which the rotational states refer, whereas the equilibrium bond length

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