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a rhodium(I) complex, Cp*Rh(CO)₂ (Cp* = pentamethylcyclopentadienyl), using a pulsed XeCl laser (308 nm) in pressurized liquid Kr as a solvent at a temperature between -80 and -120 °C and observed the formation of Cp*Rh(CO)(Kr), which was identified by infrared spectroscopy by its metal-carbonyl stretch at 1946 cm^-1. This species decayed with a

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