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polymerization parameters ( and ) and polymerization temperature:

Polymerization is possible only when . Eventually, at or above the so-called ceiling temperature , at which , formation of the high polymer does not occur.

For example, tetrahydrofuran (THF) cannot be polymerized above  = 84 °C, nor cyclo-octasulfur (S₈) below  = 159 °C. However, for many monomers, and , for polymerization in the bulk,

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