be thought of as a measure of the frequency of properly oriented collisions. It is typically determined experimentally by measuring the rate constant at a particular temperature and fitting the data to the Arrhenius equation. The pre-exponential factor is generally not exactly constant, but rather depends on the specific reaction being studied and the temperature at which the reaction is occurring.

The units of the pre-exponential factor A are identical to those of the rate constant and will vary depending on the order of the reaction.