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these solutons are treated with base:

Classically, alkylsulfonates can prepared by the Strecker sulfite alkylation, in which sulfite displaces a halide:
:

Arylsulfonates are produced by sulfonation of the arene using sulfur trioxide, sulfuric acid, or related reagents, followed by deprotonation of the resulting acid:
:
:

Alkyl and arylsulfonates also arise

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