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<p>Ligands with tightly-bound halide atoms such as <a href="page.php?w=xenon_difluoride">xenon difluoride</a> coordinate the silver, but do not themselves decompose:<br/>
:AgPF<sub>6</sub>&nbsp;+ 2&nbsp;XeF<sub>2</sub>&nbsp;-> [Ag(XeF<sub>2</sub>)<sub>2</sub>]PF<sub>6</sub>.  </p>

<p>AgPF<sub>6</sub> can act as an oxidant, forming silver metal as a by-product. For example, in solution in dichloromethane, <a href="page.php?w=ferrocene">ferrocene</a> is oxidised to <a href="page.php?w=ferrocenium_hexafluorophosphate">ferrocenium hexafluorophosphate</a>:</p><p>
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