Earl of Liverpool, who was then the Secretary of State for the Colonies and the English city of Liverpool, upon which some of the area's architecture is based.

The post office opened at Liverpool on 1 March 1825 - one of the first post offices to be opened in New South Wales. Liverpool was one of the six stations on the first line of telegraphs to be constructed in this colony.

On 26 January 1858, a telegraph office was opened at the railway station.

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