and corresponds to the shortened bond length observed in other sulfonamides. This is presumably caused by a coordinative bond between the lone pair of the amino group and the atomic orbital of the sulfur atom.

Use

Various reagents for chemical syntheses can be produced from methanesulfonamide. For example, methanesulfonamide 1, ''p''-toluenesulfonic acid 2 and 1,1-dimethoxy-2-(methylthio)ethane

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