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His eldest son, Philippe d'Orleans, was elected as a 2nd class member (i.e. an eldest son of a veteran officer) in 1890 and succeeded to first class membership in the Order upon Philippe's death.

Marriage and issue

On 30 May 1864 at St. Raphael's Church in Kingston upon Thames, England he married his paternal first cousin, Princess Marie Isabelle d'Orléans

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