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bromine water by electron-rich arenes is used in the bromine test.

The oxychlorination of benzene has been well investigated, motivated by the avoidance of HCl as a coproduct in the direct halogenation:
:This technology is not widely used however.

The Gatterman reaction can also be used to convert diazonium salts to chlorobenzenes using copper-based reagents. Owing to high cost of diazonium salts,

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