because in standard stellar evolution theory G and K giants are not far enough along in their evolution to have synthesized carbon and s-process elements and mix them to their surfaces. The discovery of the stars' binary nature resolved the puzzle, putting the source of their spectral peculiarities into a companion star which should have produced such material. The mass transfer episode is believed to be quite brief on an astronomical timescale.

Prototypical barium stars include Zeta Capricorni,