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<p>will be a set of lattice vectors  with . Then there will be  independent plane wave solutions of which any linear combination is also a solution:</p>

<p>Now let  be nonzero and small. Non-degenerate and degenerate perturbation theory, respectively, can be applied in these two cases to solve for the Fourier coefficients  of the wavefunction (correct to first order in ) and the energy eigenvalue  (correct to second order in ). An important result of this derivation is that there is no first-order shift in the energy  in the case of no degeneracy,</p><p>
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