1.Previous
3.Next

it is very difficult to experimentally achieve reversible conditions because any perturbation imposed to a system near equilibrium in a finite time forces it out of equilibrium. However, if the solicitations exerted on the system are sufficiently small and applied slowly, one can consider an electrode to be reversible. By nature, electrode reversibility depends on the experimental conditions and the way the electrode is operated. For example, electrodes used in electroplating are operated with a high over-potential to force the reduction of a

1.Previous
3.Next