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([Cu(MeCN)₆](B(C₆F₅)₄)₂, pale blue-green solid
* Hexakis(acetonitrile)ruthenium(II) tetrafluoroborate ([Ru(MeCN)₆](BF₄)₂), white, d_Ru-N = 202 pm.
* Hexakis(acetonitrile)rhodium(III) tetrafluoroborate ([Rh(MeCN)₆](BF₄)₃), a yellow solid.
* Hexakis(acetonitrile)rhenium(II) tetrafluoroborate ([Re(MeCN)₆](BF₄)₂), a yellow solid.
* Hexakis(acetonitrile)rhenium(III)

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