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The aquo ligands on iron(III) complexes are labile. This behavior is visualized by the color change brought about by reaction with thiocyanate to give a deep red thiocyanate complex.

Iron(III) with organic ligands

In the presence chelating ligands, the complex hydrolysis reactions are avoided. One of these ligands is EDTA, which is often used to dissolve iron deposits or added to fertilizers

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