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<p>the <a href="page.php?w=Mannheim_process">Mannheim process</a> for producing sodium sulfate.  The process involves intermediate formation of <a href="page.php?w=potassium_bisulfate">potassium bisulfate</a>, an exothermic reaction that occurs at room temperature:<br/>
:The second step of the process is endothermic, requiring energy input:<br/>
:</p>

<p><big>Structure and properties</big></p>
<p>Two crystalline forms are known.  Orthorhombic ?-K<sub>2</sub>SO<sub>4</sub> is the common form, but it converts to ?-K<sub>2</sub>SO<sub>4</sub> above 583&nbsp;°C.</p><p>
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